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苏州海财塑化有限公司
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Ferro Corporation PP Ferro LPP10BK38BK
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PP属于结晶型聚合物,不到一定温度其颗粒不会熔融,不像PE或PVC那样在加热过程中随着温度提高而软化。一旦达到某一温度,PP颗粒迅速融化,在几度范围内就可全部转化为熔融状态。PP的熔体粘度比较低,因此成型加工流动性良好,特别是当熔体流动速率较高时熔体粘度更小,适合于大型薄壁制品注塑成型,例如洗衣机内桶。PP属于非极性聚合物,具有良好的电绝缘性,且PP吸水性极低,电绝缘性不会受到湿度的影响。PP的介电常数、介质损耗因数都很小,不受频率及温度的影响。PP的介电强度很高,且随温度上升而增大。这些都是在湿、热环境下对电气绝缘材料有利的。另一方面PP的表面电阻很高,在一些场合使用必须先进行抗静电处理。PP是高结晶塑料,它在熔点的附近时,它的液态和固态的体积相差很大,加上它收缩时的各向异性,因此易引起不均衡收缩即缩水;因此,设计制品时,尽量避免壁厚不均匀;聚丙烯的熔体粘度小,流动性好,流长比流动长度与厚度的比值大,薄壁制品可能也能注满;但同时,它的模具制作时,精度要高,否则会批峰;因它的各向异性,制品经常是变形。收缩率为18‰;溢边值为0.03mm。聚丙烯不吸水,一般不需烘干,有时为了产品质量,也可以用60℃的温度,烘干30分钟至1个小时,以排出原料中的浮水。
长期供应 PP” 抗撞击PP、食品级PP、耐热级PP、耐候级PP、高流动PP、抗静电PP、抗紫外线PP以及吹塑级PP、挤出级PP、透明级PP 可为客户提供相应有效的报告证明、品质保证及有关性能测试报告, 如:无毒证明,COA,UL黄卡,MSDS、SGS(RoHS)、FDA、ASTM或ISO物性资料等,提供优质的售后服务与技术支持
PP---特点:密度小,强度刚度,硬度耐热性均优于低压聚乙烯,可在100度左右使用。具有良好的电性能和高频绝缘性不受湿度影响,但低温时变脆、不耐磨、易老化. 适于制作一般机械零件,耐腐蚀零件和绝缘零件PP塑胶原料化学和物理特性
PP ---是一种半结晶性材料。它比PE要更坚硬并且有更高的熔点。由于均聚物型的PP温度高于0C以上时非常脆,因此许多商业的PP材料是加入1~4%乙烯的无规则共聚物或更高比率乙烯含量的钳段式共聚物。 共聚物型的PP材料有较低的热扭曲温度(100C)、低透明度、低光泽度、低刚性,但是有有更强的抗冲击强度。PP的强度随着乙烯含量的增加而增大。PP的维卡软化温度为150C。由于结晶度较高,这种材料的表面刚度和抗划痕特性很好。PP不存在环境应力开裂问题。通常,采用加入玻璃纤维、金属添加剂或热塑橡胶的方法对PP进行改性。
PP--的流动率MFR范围在1~40。低MFR的PP材料抗冲击特性较好但延展强度较低。对于相同MFR的材料,共聚物型的强度比均聚物型的要高。 由于结晶,PP的收缩率相当高,一般为1.8~2.5%。并且收缩率的方向均匀性比PE-HD等材料要好得多。加入30%的玻璃添加剂可以使收缩率降到0.7%。
均聚物型和共聚物型的PP材料都具有优良的抗吸湿性、抗酸碱腐蚀性、抗溶解性。然而,它对芳香烃(如苯)溶剂、氯化烃(四氯化碳)溶剂等没有抵抗力。PP也不象PE那样在高温下仍具有抗氧化性。
PP---范围汽车工业(主要使用含金属添加剂的PP:挡泥板、通风管、风扇等),器械(洗碗机门衬垫、干燥机通风管、洗衣机框架及机盖、冰箱门衬垫等),日用消费品(草坪和园艺设备如剪草机和喷水器等)
聚丙烯PP性能概述:
PP物理性能:无毒、无臭、无味的乳白色高结晶聚合物;密度:0.90~0.91g/cm3,是目前所有塑料中最轻的品种之一;吸水率差,仅0.01%;
PP力学性能:结晶度高,结构规整,强度和硬度、以及弹性都比不上HDPE;但在室温和低温下,由于本身结构规整度高,所以其冲击强度较差,分子量增加的时候,冲击强度也加强,但如果会使成型加工性变差,PP最突出的性能就是抗弯曲疲劳性。
PP热性能:PP具有良好的耐热性,熔点在164~170℃。在不受外力的情况下,150℃也不会变形。在低于-35℃会发生脆化,耐寒性不如PE。
PP化学性能:化学稳定性良好,除了能被浓硫酸、浓硝酸侵蚀外,对其他化学药剂都比较稳定。化学性随结晶度的增加还有所提高。
PP电能性:由于它的吸水率差,因此它几乎不吸水,所以不受湿度的影响,其绝缘性非常好。
PP耐候性:PP对紫外线很敏感,加入氧化锌等填料会改善其老化性能。
供应韩国油化PP:
PP 4017H均聚物,一般目的,MI=24g/10min。
PP 4017M均聚物,用于薄壁部件、电器用具,MI=14。
PP 4018均聚物,清晰度高,医疗级,MI=19。
PP 5010高拉伸强度,均聚物,MI=10g/10min。
PP 5010U高拉伸强度,均聚物,耐气候影响性能良好。
PP 5012均聚物,MI=2.0。
PP 5012U高拉伸强度,均聚物,耐气候影响性能良好,MI=1.8g/10min。
PP 5014均聚物,一般目的,MI=3.2g/10min。
PP 5014L均聚物,可加工性良好,MI=3.0。
PP 5014U均聚物,耐气候影响性能良好,MI=3.5g/10min。
供应韩国SEETEC—PP:
PP H1500主要性能:均聚物,流动性高,FDA认证,MI=12。
PP H1501主要性能:均聚物,刚性高,流动性高,食品级,MI=17。
PP H1615主要性能:均聚物,刚性高,抗刮伤,食品级,高结晶,耐热性高,MI=18。
PP H5300主要性能:均聚物,可加工性良好,良好的拉伸性,食品级,MI=3.5。
PP M1400主要性能:共聚物,刚性良好,流动性高,抗撞击性良好,食品级,MI=8。
PP M1500主要性能:共聚物,刚性高,抗撞击性高,流动性高,MI=16。
供应马来大腾石化PP:
PP/PM801:刚性良好,抗撞击性良好,食品级,生产阶段快,中等透明,薄壁部件,MI=50g/10min。
PP/PM802:均聚物,MI=40g/10min。
PP/PM803:低翘曲性,可控流变,食品级,高流动,MI=50g/10min。
PP/PM925:高光泽,良好的剥离性,抗气体褪色性,MI=25。
PP/SM668:加有澄清剂、无规共聚物、防潮、清晰度高、抗撞击性良好、中等硬度、FDA认证。主要参数:熔流率20g/10min。
PP/SM669:加有澄清剂、无规共聚物、高流动性、尺寸稳定性良好、清晰度高、中等硬度、抗撞击性良好。主要参数:熔流率30g/10min。
PP/SM701:抗冲共聚物,MI=27。
PP/SM790:抗冲共聚物,良好的抗蠕变性,MI=8.0。
PP/SM791:抗撞击性良好,高流动MI=30,食品级,抗冲共聚物。
PP/SM840:低温韧性,良好的表面光洁度,食品级,抗冲共聚物,高流动MI=35。
供应韩国LG—玻纤增强PP:
PP GP-2100主要性能:10%玻纤增强,MI=15g/10min,耐热145度。
PP GP-2200主要性能:20%玻纤增强,MI=8.0g/10min,耐热150度。
PP GP-2201F主要性能:20%玻纤增强,耐热性高142度,阻燃V1,高强度,MI=g/10min。
PP GP-2300主要性能:30%玻纤增强,一般目的,MI=7.0g/10min,耐热155度。
PP HI-5302A主要性能:30%玻纤增强,冲击调节器,尺寸稳定性良好,改良抗撞击性,高抗冲,MI=25。
pp
聚丙烯英文名称:Polypropylene,简称:PP,俗称:百折胶。聚丙烯是聚α-烯烃的代表,由丙烯聚合而制得的一种热塑性树脂,其单体是丙烯CH2=CH-CH3。根据引发剂和聚合工艺的不同,聚丙烯可以分为等规聚丙烯和无规聚丙烯和间规聚丙烯三种构型。等规聚丙烯易形成结晶态,结晶度高达95%以上,分子量在8-15万之间,赋予他良好的抗热和抗溶剂性;无规聚丙烯在室温下是一种非结晶的、微带粘性的白色蜡状物,分子量低,在3000-10000,结构不规整缺乏内聚力,应用较少。
聚丙烯
PP聚丙烯
商标名称: 例如,Asota® Asota GmbH
最高持续操作温度
干燥情况
90 ºC
最高峰温度 100 ºC
特殊密度 0.91 g/cm³
抗拉强度 大约120-150 daN/5 cm
熔化温度 162 - 176 ºC
吸潮度 0%
LOI(极限氧指数) 18
特性 优点
? 防酸和碱的能力很强
? 防有机溶剂的能力强
? 特殊密度低 缺点
? 最高操作温度低
? 易于在氧化过程发生老化
应用范围
汽车工业(主要使用含金属添加剂的PP:挡泥板、通风管、风扇等),器械(洗碗机门衬垫、干燥机通风管、洗衣机框架及机盖、冰箱门衬垫等),日用消费品(草坪和园艺设备如 剪草机和喷水器等)。
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